User verstrix just showed me the same errors as we see in this forums post: https://forums.funtoo.org/topic/4805-cant-get-sound-to-work-solved/
The solution in the forums post worked for him as well. Basically:
emerge media-libs/alsa-lib consolekit
rc-update add consolekit default
/etc/init.d/consolekit start
at which point `pulseaudio` and `pavucontrol` should both work as expected